Oxygen → HCID 131726455, compound

HRID 1353017Notes

Reaction equation

HRID 1353017 reaction equation
C[SiH](C)CCC(F)(C=C)C(F)F.[B:13]([CH2:22][CH2:23][CH2:24][CH3:25])([CH2:18][CH2:19][CH2:20][CH3:21])[CH2:14][CH2:15][CH2:16][CH3:17].[O:26]=[O:27]>C(Cl)Cl>[B:13]([CH2:18][CH2:19][CH2:20][CH3:21])([CH2:22][CH2:23][CH2:24][CH3:25])[CH2:14][CH2:15][CH2:16][CH3:17].[O:26]=[O:27]

Participants

5

Reactant 3

HCID 977OxygenHCID 31216TributylboraneHCID 123367077HCID 123367077, compound

Product 1

HCID 131726455HCID 131726455, compoundYield 40%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

The radical polymerization was conducted in a 70 ml stainless autoclave equipped with a magnetic stirrer. After adding 3.0 g of CF2═CFCH2CH2Si(CH3)2H, 0.1 g of (n-C4H9)3B, and 20 ml CH2Cl2 under argon, 20 ml of VDF and 5 ml of HFP were introduced into the reactor under vacuum by condensing the monomers at liquid nitrogen temperatures. About 15 ml of O2 was then introduced to initiate the polymerization. The autoclave was slowly warmed to room temperature and then immersed in an oil bath at 80° C. for 20 hours. After recovering the unreacted monomers, the slurry was dried under vacuum to obtain 4.5 g of a white polymer powder, with 40% yield.

Workup

  1. customThe radical polymerization
  2. customequipped with a magnetic stirrer
  3. addition20 ml of VDF and 5 ml of HFP were introduced into the reactor under vacuum by condensing the monomers at liquid nitrogen temperatures
  4. customthe polymerization
  5. customAfter recovering the unreacted monomers
  6. customthe slurry was dried under vacuum

Sources & evidence

ORD record
ord-2c9bba77389e46e7a894c0b777008389
Source dataset
uspto-grants-2007_05
Patent number
US07220807B2

Reaction notes

Loading…