Oxygen → HCID 131726455, compound

HRID 1353020Notes

Reaction equation

HRID 1353020 reaction equation
[B:1]([CH2:10][CH2:11][CH2:12][CH3:13])([CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH2:4][CH3:5].[O:14]=[O:15]>C(Cl)Cl>[B:1]([CH2:6][CH2:7][CH2:8][CH3:9])([CH2:10][CH2:11][CH2:12][CH3:13])[CH2:2][CH2:3][CH2:4][CH3:5].[O:14]=[O:15]

Participants

4

Reactant 2

HCID 977OxygenHCID 31216Tributylborane

Product 1

HCID 131726455HCID 131726455, compoundYield 60%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

The radical polymerization was conducted in a 70 ml stainless autoclave equipped with a magnetic stirrer. After adding 0.84 g of CF2═CFCH2CH2OSi(CH3)3, 91 mg of (n-C4H9)3B, and 20 ml CH2Cl2 under argon, 25 ml of VDF was introduced into the reactor under vacuum by condensing the monomers at liquid nitrogen temperatures. About 4 ml of O2 was then introduced to initiate the polymerization. The autoclave was slowly warmed to room temperature and then kept at room temperature for 20 hours. After recovering the unreacted monomers, the slurry was poured into methanol, and the participated polymer powder was dried under vacuum for 24 hours at 80° C. The overall polymer yield was about 60%, and the polymers molecular weight determined by intrinsic viscosity was Mv=53,000 g/mole. The composition of the copolymer, containing 1.5 mole % of CF2═CFCH2CH2OSi(CH3)3 units, was determined by 1H NMR spectra.

Workup

  1. customThe radical polymerization
  2. customequipped with a magnetic stirrer
  3. addition25 ml of VDF was introduced into the reactor under vacuum by condensing the monomers at liquid nitrogen temperatures
  4. customthe polymerization
  5. customAfter recovering the unreacted monomers
  6. additionthe slurry was poured into methanol
  7. customthe participated polymer powder was dried under vacuum for 24 hours at 80° C

Sources & evidence

ORD record
ord-d881860d0b3b44d2b2a9afef64dc0952
Source dataset
uspto-grants-2007_05
Patent number
US07220807B2

Reaction notes

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