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HRID1355301

反应详情

EQUATION

反应方程式

HRID 1355301 的结构方程式

REACTANTS

反应物

3
结构：OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)CO
HCID5780

D-Glucitol

C6H14O6

结构：CCCCN(CCO)CCCC
HCID7621

2-N-Dibutylaminoethanol

C10H23NO

结构：OB(O)O
HCID7628

Boric acid (H3BO3)

H3BO3

PRODUCTS

生成物

1
结构：CCCCN(CCO)CCCC.OB(O)O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)CO
HCID86588639

未命名化合物

收率 86.3%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：Cc1ccccc1
溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

N,N-dibutylethanolamine/sorbitol borate was prepared as follows. Boric acid (10.3 grams), sorbitol (30.4 grams), and N,N-dibutylethanolamine (28.9 grams) were added to a 250 milliliter flask. One hundred fifty milliliters of toluene was then added. The reaction was allowed to proceed overnight at 110° C., and the byproduct water (˜9 grams) was continuously removed from the reaction by azeotropic distillation. The final solution was evaporated to remove toluene under vacuum, and a yellowish resinous product (˜60 grams) of N,N-dibutylethanolamine/sorbitol borate was obtained.

WORKUP

后处理

  1. customN,N-dibutylethanolamine/sorbitol borate was prepared
  2. customthe byproduct water (˜9 grams) was continuously removed from the reaction by azeotropic distillation
  3. customThe final solution was evaporated
  4. customto remove toluene under vacuum