Benzyl mercaptan → HCID 18507355, compound

HRID 1355790Notes

Reaction equation

HRID 1355790 reaction equation
[NH2:1][C:2]1[N:7]=[C:6]([S:8]([CH3:11])(=O)=O)[C:5]([C:12]#[N:13])=[C:4]([C:14]2[CH:19]=[C:18]([O:20][CH3:21])[C:17]([O:22][CH3:23])=[C:16]([O:24][CH3:25])[CH:15]=2)[N:3]=1.C(S)[C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1.C1CCN2C(=NCCC2)CC1>COCCOC>[NH2:1][C:2]1[N:7]=[C:6]([S:8][CH2:11][C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)[C:5]([C:12]#[N:13])=[C:4]([C:14]2[CH:19]=[C:18]([O:20][CH3:21])[C:17]([O:22][CH3:23])=[C:16]([O:24][CH3:25])[CH:15]=2)[N:3]=1

Participants

5

Reactant 3

HCID 7509Benzyl mercaptanHCID 811841,8-Diazabicyclo(5.4.0)undec-7-eneHCID 18507557HCID 18507557, compound

Product 1

HCID 18507355HCID 18507355, compound

Reagents, catalysts & solvents 1

HCID 80711,2-DimethoxyethaneSolvent

Procedure

From 2-amino-4-methanesulfonyl-6-(3,4,5-trimethoxy-phenyl)-pyrimidine-5-carbonitrile, benzyl mercaptan and DBU in DME. ES-MS m/e (%): 409 (M+H+, 100).

Sources & evidence

ORD record
ord-795cc14135474679a65daede5b9f8492
Source dataset
uspto-grants-2003_07
Patent number
US06586441B2

Reaction notes

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