Potassium Carbonate → HCID 18509491, compound

HRID 1356811Notes

Reaction equation

HRID 1356811 reaction equation
[CH3:1][C:2]([CH3:11])([CH3:10])[C:3]#[C:4][CH:5]=[CH:6][CH2:7][NH:8][CH3:9].C(=O)([O-])[O-].[K+].[K+].[Br:18][C:19]1[CH:26]=[CH:25][CH:24]=[CH:23][C:20]=1[CH2:21]Br>>[CH3:1][C:2]([CH3:11])([CH3:10])[C:3]#[C:4]/[CH:5]=[CH:6]/[CH2:7][N:8]([CH2:21][C:20]1[CH:23]=[CH:24][CH:25]=[CH:26][C:19]=1[Br:18])[CH3:9]

Participants

4

Reactant 3

HCID 11430Potassium CarbonateHCID 769652-Bromobenzyl bromideHCID 53427009N,6,6-trimethylhept-2-en-4-yn-1-amine

Product 1

HCID 18509491HCID 18509491, compoundYield 56.5%

Procedure

The procedure described in Example 1 was repeated, except that N-(6,6-dimethyl-2-hepten-4-ynyl)methylamine (1.96 g; 13.0 mmol), potassium carbonate (1.44 g; 13.6 mmol), and 2-bromobenzylbromide (3.25 g; 13.0 mmol) were used, to thereby yield 2.35 g of the target compound (yield: 56.5%).

Sources & evidence

ORD record
ord-1fae400998064a1a9660fb0eb8bad83d
Source dataset
uspto-grants-2003_07
Patent number
US06586633B1

Reaction notes

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