Stannous Chloride → Ethyl 3-(3-aminophenyl)3-benzoylamino-propionate

HRID 1357069노트

반응식

HRID 1357069 반응식
[C:1]([NH:9][CH:10]([C:17]1[CH:22]=[CH:21][CH:20]=[C:19]([N+:23]([O-])=O)[CH:18]=1)[CH2:11][C:12]([O:14][CH2:15][CH3:16])=[O:13])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Sn](Cl)Cl>>[NH2:23][C:19]1[CH:18]=[C:17]([CH:10]([NH:9][C:1](=[O:8])[C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[CH2:11][C:12]([O:14][CH2:15][CH3:16])=[O:13])[CH:22]=[CH:21][CH:20]=1

참가 물질

3

반응물 2

HCID 24479Stannous ChlorideHCID 3816281Ethyl 3-benzoylamino-3-(3-nitrophenyl)-propionate

생성물 1

HCID 18505414Ethyl 3-(3-aminophenyl)3-benzoylamino-propionate

실험 절차

Corresponding to Example 3b, 3 g of (4a) were reduced using tin-(II) dichloride. A white solid was obtained (yield: 2.6 g).

후처리

  1. customA white solid was obtained (yield: 2.6 g)

출처 및 근거

ORD 기록
ord-b17c282050104bea966f9d322c946da5
출처 데이터셋
uspto-grants-2003_07
특허 번호
US06589972B2

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