Acetic Acid → HCID 178424777, compound

HRID 1358058Notes

Reaction equation

HRID 1358058 reaction equation
[CH3:1][C-:2]1[C:6]([CH3:7])=[C:5](C)[C:4]([CH3:9])=[C:3]1[CH3:10].[C-]1([C:16]([N:18]=[N+]=[N-])=[O:17])C=CC=C1.[Fe+2:21].C(O)(=O)C>C(OC(=O)C)(=O)C>[CH3:7][C-:6]1[CH:5]=[C:4]([CH3:9])[C:3]([CH3:10])=[C:2]1[CH3:1].[C-:4]1([CH2:9][C:16]([NH2:18])=[O:17])[C:3]([CH3:10])=[CH:2][CH:6]=[CH:5]1.[Fe+2:21]

Participants

4

Reactant 2

HCID 176Acetic AcidHCID 178424888HCID 178424888, compound

Product 1

HCID 178424777HCID 178424777, compoundYield 162.8%

Reagents, catalysts & solvents 1

HCID 7918Acetic AnhydrideSolvent

Procedure

0.13 g (0.4 mmol) of 1′,2′,3′,4′,5′-pentamethylferrocene-1-carboxylic acid azide are stirred with 0.5 ml of acetic acid in 10 ml of acetic anhydride at 80° c for five hours. Aqueous work-up gives 0.102 g of 1′,2′,3′,4′,5-pentamethylferrocen-1-yl-acetamide.

Sources & evidence

ORD record
ord-6ee2614fb0f6436994b5253b706e2552
Source dataset
uspto-grants-2003_07
Patent number
US06593437B1

Reaction notes

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