Acetate → [3,4,5-Triacetyloxy-6-[4-cyclopropyl-3-[[5-(furan-2-yl)-1,3-thiazol-2-yl]methyl]phenyl]oxan-2-yl]methyl acetate

HRID 136270Notes

Reaction equation

HRID 136270 reaction equation
[C:1]([CH3:2])(=[O:3])[O:4][CH:5]1[CH:6]([CH2:37][O:38][C:39]([CH3:40])=[O:41])[O:7][CH:8]([c:19]2[cH:20][c:21]([CH2:26][c:27]3[s:28][c:29](-[c:32]4[o:33][cH:34][cH:35][cH:36]4)[cH:30][n:31]3)[c:22]([Br:25])[cH:23][cH:24]2)[CH:9]([O:15][C:16]([CH3:17])=[O:18])[CH:10]1[O:11][C:12]([CH3:13])=[O:14].[C:72](=[O:73])([O-:74])[O-:75].[CH:42]1([B:45]([OH:46])[OH:47])[CH2:43][CH2:44]1.[CH:53]1([PH+:54]([CH:55]2[CH2:56][CH2:57][CH2:58][CH2:59][CH2:60]2)[CH:61]2[CH2:62][CH2:63][CH2:64][CH2:65][CH2:66]2)[CH2:67][CH2:68][CH2:69][CH2:70][CH2:71]1.[Cs+:76].[Cs+:77].[F:48][B-:49]([F:50])([F:51])[F:52].[O-:79][C:80]([CH3:81])=[O:82].[O-:83][C:84]([CH3:85])=[O:86].[Pd+2:78]>>[C:1]([CH3:2])(=[O:3])[O:4][CH:5]1[CH:6]([CH2:37][O:38][C:39]([CH3:40])=[O:41])[O:7][CH:8]([c:19]2[cH:20][c:21]([CH2:26][c:27]3[s:28][c:29](-[c:32]4[o:33][cH:34][cH:35][cH:36]4)[cH:30][n:31]3)[c:22]([CH:42]3[CH2:43][CH2:44]3)[cH:23][cH:24]2)[CH:9]([O:15][C:16]([CH3:17])=[O:18])[CH:10]1[O:11][C:12]([CH3:13])=[O:14]

Participants

9

Reactant 8

HCID 175Acetate2×HCID 19660Carbonate IonHCID 26255TetrafluoroborateHCID 104967Cesium cation2×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 2760897Cyclopropylboronic acidHCID 4866470CID 4866470HCID 123782496[3,4,5-Triacetyloxy-6-[4-bromo-3-[[5-(furan-2-yl)-1,3-thiazol-2-yl]methyl]phenyl]oxan-2-yl]methyl acetate

Product 1

HCID 77393927[3,4,5-Triacetyloxy-6-[4-cyclopropyl-3-[[5-(furan-2-yl)-1,3-thiazol-2-yl]methyl]phenyl]oxan-2-yl]methyl acetate

Sources & evidence

ORD record
ord-621304ccbda44d6b9445ac06739a3789
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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