Nitric Acid → 2-Chloro-5-nitrobenzoic acid

HRID 1363407Notes

Reaction equation

HRID 1363407 reaction equation
[Cl:1][C:2]1[CH:10]=[CH:9][CH:8]=[CH:7][C:3]=1[C:4]([OH:6])=[O:5].[N+:11]([O-])([OH:13])=[O:12].OS(O)(=O)=O>>[Cl:1][C:2]1[CH:10]=[CH:9][C:8]([N+:11]([O-:13])=[O:12])=[CH:7][C:3]=1[C:4]([OH:6])=[O:5]

Participants

4

Reactant 3

HCID 944Nitric AcidHCID 1118Sulfuric AcidHCID 83742-Chlorobenzoic Acid

Product 1

HCID 172872-Chloro-5-nitrobenzoic acid

Procedure

2-Chlorobenzoic acid (2 g, 12.7 mmol) was added with stirring at 25° C. to a nitrating mixture (20 mL) prepared from 1:1 HNO3 (70%) and H2SO4 (98%). It was stirred for 1 h. and poured into ice water. The title compound obtained was filtered and dried.

Sources & evidence

ORD record
ord-6c7678d8d47d4b74a6d7cb13a40bb8b1
Source dataset
uspto-grants-2011_02
Patent number
US07884127B2

Reaction notes

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