m-Chloroperbenzoic acid → HCID 66958436, compound

HRID 1364036Notes

Reaction equation

HRID 1364036 reaction equation
[CH:1]1[CH:10]=[CH:9][CH:8]=[C:7]2[C:2]=1[C:3]1[N:13]3[CH2:14][CH2:15][CH2:16][N:17]([C:19]([O:21][C:22]([CH3:25])([CH3:24])[CH3:23])=[O:20])[CH2:18][C:12]3=[N:11][C:4]=1[CH:5]=[N:6]2.C1C=C(Cl)C=C(C(OO)=[O:34])C=1>>[O-:34][N+:6]1[C:7]2[C:2](=[CH:1][CH:10]=[CH:9][CH:8]=2)[C:3]2[N:13]3[CH2:14][CH2:15][CH2:16][N:17]([C:19]([O:21][C:22]([CH3:25])([CH3:24])[CH3:23])=[O:20])[CH2:18][C:12]3=[N:11][C:4]=2[CH:5]=1

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 66958550HCID 66958550, compound

Product 1

HCID 66958436HCID 66958436, compound

Procedure

The general method described in Part E of Example 4 was used to treat tert-butyl 11,12-dihydro-8H-[1,4]diazepino[1′,2′:1,2]imidazo[4,5-c]quinoline-9(10H)-carboxylate (30.0 g, 88.6 mmol) with mCPBA (23.8 g of 77% pure material, 138 mmol) to provide tert-butyl 5-oxido-11,12-dihydro-8H-[1,4]diazepino[1′,2′:1,2]imidazo[4,5-c]quinoline-9(10H)-carboxylate. The product was not dried over magnesium sulfate but was dried under high vacuum overnight.

Sources & evidence

ORD record
ord-527c91c1103a47978fbfb0887b5f317b
Source dataset
uspto-grants-2011_02
Patent number
US07888349B2

Reaction notes

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