HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bromine → HCID 66932810, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bromine | HCID 24408 | — |
| Reactant | 5-[4-(Methylsulfanyl)phenyl]cyclohexane-1,3-dione | HCID 9991632 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | HCID 66932810 | HCID 66932810 | 71.5% |
Reaction Steps
To a stirred solution of 5-[4-(methylthio)phenyl]cyclohexane-1,3-dione (1.08 g, 4.6 mmol) in AcOH (10 mL) at r.t. was added bromine (0.74 g, 0.23 mL, 4.6 mmol) dropwise. The reaction was then carried out according to Method A to give the title compound (1.03 g, 70%) as a white solid. LCMS (ES+) 314.9 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07888344B2 |
| Source dataset | uspto-grants-2011_02 |
| ORD ID | ord-ecad9787450c49a2a8948594fe3e352c |
| Source note | uspto-grants-2011_02 |