HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl (+/-)-10,11 dihydro-3-methoxy-5H-dibenzo[a,d]cycloheptene-10-acetate → Ethyl (+/-)-10,11-dihydro-3-hydroxy-6-methyl-5H-dibenzo[a,d]cycloheptene-10-acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl (+/-)-10,11 dihydro-3-methoxy-5H-dibenzo[a,d]cycloheptene-10-acetate | HCID 15462070 | — |
| Reactant | Ethyl (+/-)-10,11-dihydro-3-methoxy-6-methyl-5H-dibenzo[a,d]cycloheptene-10-acetate | HCID 86585473 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Ethyl (+/-)-10,11-dihydro-3-hydroxy-6-methyl-5H-dibenzo[a,d]cycloheptene-10-acetate | HCID 53895967 | — |
Reaction Steps
According to the procedure of Preparation 10 (g), except substituting ethyl (±)-10,11-dihydro-3-methoxy-6-methyl-5H-dibenzo[a,d]cycloheptene-10-acetate for the ethyl (±)-10,11-dihydro-3-methoxy-5H-dibenzo[a,d]cycloheptene-10-acetate, the title compound was obtained as a white solid after trituration with MeOH: MS (ES) m/e 311.2 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06576643B2 |
| Source dataset | uspto-grants-2003_06 |
| ORD ID | ord-96e16f48f00b4927b396d3ef3ba23f21 |
| Source note | uspto-grants-2003_06 |