HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium hydride → HCID 69959769, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | Diethyl (cyanomethyl)phosphonate | HCID 75676 | — |
| Reactant | 2-Methoxy-1-naphthaldehyde | HCID 79352 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 69959769 | HCID 69959769 | — |
Reaction Steps
Starting from 5 g (26.85 mmol) of 2-methoxynaphthaldehyde in 30 ml of anhydrous THF in the presence of 1.3 g (1.2 eq) of NaH (60% in oil) in 15 ml of anhydrous THF and 6.5 ml (1.2 eq) of diethyl cyanomethylphosphonate, the title product is obtained in the form of a white solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06583319B1 |
| Source dataset | uspto-grants-2003_06 |
| ORD ID | ord-d8b9ef773b694a8d93e28a85ebdb6893 |
| Source note | uspto-grants-2003_06 |