Ethyl Glycolate → HCID 18512104, compound

HRID 1370840Notes

Reaction equation

[CH2:1]([N:8]([CH2:19][C:20]1[CH:34]=[CH:33][C:23]([O:24][C:25]2[CH:26]=[CH:27][C:28]([Br:32])=[C:29]([OH:31])[CH:30]=2)=[CH:22][CH:21]=1)[C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([N+:15]([O-:17])=[O:16])[C:10]=1[CH3:18])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:35]([O:39][CH2:40]C)(=O)[CH2:36]O>>[CH2:1]([N:8]([CH2:19][C:20]1[CH:21]=[CH:22][C:23]([O:24][C:25]2[CH:26]=[CH:27][C:28]([Br:32])=[C:29]([O:31][CH2:36][CH2:35][O:39][CH3:40])[CH:30]=2)=[CH:33][CH:34]=1)[C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([N+:15]([O-:17])=[O:16])[C:10]=1[CH3:18])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

Reactant 2

HCID 12184Ethyl Glycolate

HCID 18512148HCID 18512148, compound

Product 1

HCID 18512104HCID 18512104, compound

Procedure

The product from example 63F was processed as described in Example 62A substituting 2-methoxyethanol for ethyl glycolate to provide the title compound.

Sources & evidence

ORD record: ord-e931147dced348dabdf7b95f73f97556
Source dataset: uspto-grants-2003_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06583180B2

Reaction notes

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