(1,1'-Biphenyl)-4-carboxaldehyde → HCID 12118589, compound

HRID 1373384Notes

Reaction equation

HRID 1373384 reaction equation
[C:1]1([C:7]2[CH:14]=[CH:13][C:10]([CH:11]=O)=[CH:9][CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C1(C2C=CC=CC=2)C=CC=CC=1C1[CH:26]=[C:25]([C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][N:28]=2)[N:24]=[C:23]([C:33]2[CH:38]=[CH:37][CH:36]=[CH:35][N:34]=2)[CH:22]=1>>[C:7]1([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH:14]=[CH:13][C:10]([C:11]2[CH:26]=[C:25]([C:27]3[CH:32]=[CH:31][CH:30]=[CH:29][N:28]=3)[N:24]=[C:23]([C:33]3[CH:38]=[CH:37][CH:36]=[CH:35][N:34]=3)[CH:22]=2)=[CH:9][CH:8]=1

Participants

3

Reactant 2

HCID 76689(1,1'-Biphenyl)-4-carboxaldehydeHCID 86593622HCID 86593622, compound

Product 1

HCID 12118589HCID 12118589, compound

Procedure

This compound is prepared analogously to the procedure described above for the preparation of the ligand L12 in Example 12, but 4-phenyl benzaldehyde is used as carbonyl component. 4′-Biphenylyl-[2,2′;6′,2″]terpyridine, white solid. 13C-NMR (90 MHz, CDCl3): 156.6 (quart.); 156.3 (quart.); 150.0 (quart.); 149.5 (tert.); 142.2 (quart.); 140.8 (quart.); 137.6 (quart.); 136.9 (tert.); 129.3 (tert.); 128.1 (tert.); 128.0 (tert.); 127.9 (tert.); 126.3 (tert.); 124.2 (tert.); 121.8 (tert.); 119.1 (tert.).

Workup

  1. customThis compound is prepared analogously to the procedure

Sources & evidence

ORD record
ord-9c463053871445279cfcd6043a7798cb
Source dataset
uspto-grants-2007_01
Patent number
US07161005B2

Reaction notes

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