2-(Methylamino)ethanol → HCID 58781418, compound

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Reaction Steps

This compound is prepared in a manner analogous to that described in Example 7 with 4′-chloro-[2,2′;6′,2″]terpyridine, but instead the trichloro-substituted terpyridine L22 from Example 28, and 2-methylaminoethanol as amine component are used. 2-({4′,4″-Bis[(2-hydroxy-ethyl)-methyl-amino]-[2,2′;6′,2′]terpyridin-4-yl}methyl-amino)-ethanol, white solid. 13 C-NMR (90 MHz, DMSO-d6): 156.4 (quart.); 155.7 (quart.); 155.3 (quart.); 154.4 (quart.); 149.2 (tert.); 106.7 (tert.); 103.4 (tert.); 103.1 (tert.); 58.4 (2 signals, sec.); 58.2 (sec.); 53.6 (sec.); 53.5 (2 signals, sec.); 38.6 (prim.); 38.3 (2 signals, prim.).

Provenance & Evidence