Dodecane → Bromine

HRID 1373514Notes

Reaction equation

HRID 1373514 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Br:13][Br:14]>>[Br:13][Br:14].[CH2:12]([Br:13])[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Participants

4

Reactant 2

HCID 8182DodecaneHCID 24408Bromine

Product 2

HCID 89191-BromododecaneHCID 24408BromineYield 100%

Procedure

Pressurized dodecane liquid is mixed with bromine in a 10:1 molar ratio. The mixture is passed through a tubular reactor held at 250° C. 100% bromine conversion is obtained with 90% selectivity to dodecylbromide.

Workup

  1. customThe mixture is passed through a tubular reactor
  2. customheld at 250° C

Sources & evidence

ORD record
ord-c94afa98afc94061902f13cdd78ae057
Source dataset
uspto-grants-2007_01
Patent number
US07161050B2

Reaction notes

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