Sodium ion → 2-(6-bromo-9-chloro-1-{[2-(trimethylsilyl)ethoxy]methyl}-1H-phenanthro[9,10-d]imidazol-2-yl)isophthalonitrile

HRID 137502Notes

Reaction equation

HRID 137502 reaction equation
[Br:1][c:2]1[cH:3][c:4]2[c:5]3[cH:6][c:7]([Cl:29])[cH:8][cH:9][c:10]3[c:11]3[c:12]([nH:13][c:14](-[c:16]4[c:17]([C:18]#[N:19])[cH:20][cH:21][cH:22][c:23]4[C:24]#[N:25])[n:15]3)[c:26]2[cH:27][cH:28]1.[CH2:41]1[O:42][CH2:43][CH2:44][CH2:45]1.[CH3:32][Si:33]([CH2:34][CH2:35][O:36][CH2:37][Cl:38])([CH3:39])[CH3:40].[H-:31].[Na+:30]>>[Br:1][c:2]1[cH:3][c:4]2[c:5]3[cH:6][c:7]([Cl:29])[cH:8][cH:9][c:10]3[c:11]3[c:12]([n:13][c:14](-[c:16]4[c:17]([C:18]#[N:19])[cH:20][cH:21][cH:22][c:23]4[C:24]#[N:25])[n:15]3[CH2:37][O:36][CH2:35][CH2:34][Si:33]([CH3:32])([CH3:39])[CH3:40])[c:26]2[cH:27][cH:28]1

Participants

6

Reactant 5

HCID 923Sodium ionHCID 8028TetrahydrofuranHCID 166653HydrideHCID 27242712-Chloromethyl 2-(trimethylsilyl)ethyl etherHCID 178509773HCID 178509773, compound

Product 1

HCID 866148732-(6-bromo-9-chloro-1-{[2-(trimethylsilyl)ethoxy]methyl}-1H-phenanthro[9,10-d]imidazol-2-yl)isophthalonitrile

Sources & evidence

ORD record
ord-42f80ab7e305433d9ac7f8508af948b0
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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