Potassium Carbonate → HCID 22916352, compound

HRID 1376387Notes

Reaction equation

HRID 1376387 reaction equation
[C:1]1([C:7]2[C:11]([C:12]3[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=3)=[N:10][C:9](=[O:18])[N:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Br[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][C:27]([O:29][CH2:30][CH3:31])=[O:28].C(=O)([O-])[O-].[K+].[K+]>CC(=O)CC>[C:1]1([C:7]2[NH:8][C:9](=[O:18])[N:10]([CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][C:27]([O:29][CH2:30][CH3:31])=[O:28])[C:11]=2[C:12]2[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=2)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 731364,5-Diphenyl-2H-imidazol-2-oneHCID 264813Ethyl 8-bromooctanoate

Product 1

HCID 22916352HCID 22916352, compound

Reagents, catalysts & solvents 1

HCID 6569Methyl Ethyl KetoneSolvent

Procedure

4,5-Diphenylimidazol-2-one was treated with ethyl 8-bromooctanoate and potassium carbonate in butanone to give after work-up the title compound, m.p. 78°-79° C, Found:C, 73.7;H, 7.4;N, 6.7%;C25H30N2O3 requires: C, 73.9;H, 7.4;N, 6.9%

Sources & evidence

ORD record
ord-bd382c765cd34f3fa6d2c11b82206577
Source dataset
uspto-grants-1997_09
Patent number
US05663053

Reaction notes

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