HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl chloride → 2-(N-benzoylimino)-4,4'-dinitrobiphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl chloride | HCID 7412 | — |
| Reactant | 4,4'-Dinitro(1,1'-biphenyl)-2-amine | HCID 93265 | — |
| Catalyst | 4-(Dimethylamino)pyridine | HCID 14284 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | 2-(N-benzoylimino)-4,4'-dinitrobiphenyl | HCID 86751211 | — |
Reaction Steps
In the first step, 4,4'-dinitro-2-biphenylamine is reacted with benzoyl chloride in the presence of 4-dimethylamine pyridine in N-methyl-2-pyrrolidinone (NMP) to give 2-(N-benzoylimino)-4,4'-dinitrobiphenyl. The hydrogenation of the latter in N,N-dimethylacetamide (DMAc) at room temperature with 10% Pd/C as a catalyst provides the desired 2-(N-benzoylimino)-4,4'-diaminobiphenyl.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05663437 |
| Source dataset | uspto-grants-1997_09 |
| ORD ID | ord-971ffbe07f6544068395fb7fd26401a4 |
| Source note | uspto-grants-1997_09 |