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HRID1377006

反应详情

EQUATION

反应方程式

HRID 1377006 的结构方程式

REACTANTS

反应物

2
结构：O=C(Cl)c1ccccc1
HCID7412

Benzoyl chloride

C7H5ClO

结构：Nc1cc([N+](=O)[O-])ccc1-c1ccc([N+](=O)[O-])cc1
HCID93265

4,4'-Dinitro-2-biphenylamine

C12H9N3O4

PRODUCTS

生成物

1
结构：O=C(N=C1CC([N+](=O)[O-])=CC=C1c1ccc([N+](=O)[O-])cc1)c1ccccc1
HCID86751211

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CN(C)c1ccncc1
催化剂HCID14284

N,N-Dimethylpyridin-4-amine

C7H10N2

结构：CN1CCCC1=O
溶剂HCID13387

N-Methyl-2-pyrrolidone

C5H9NO

PROCEDURE

实验过程

In the first step, 4,4'-dinitro-2-biphenylamine is reacted with benzoyl chloride in the presence of 4-dimethylamine pyridine in N-methyl-2-pyrrolidinone (NMP) to give 2-(N-benzoylimino)-4,4'-dinitrobiphenyl. The hydrogenation of the latter in N,N-dimethylacetamide (DMAc) at room temperature with 10% Pd/C as a catalyst provides the desired 2-(N-benzoylimino)-4,4'-diaminobiphenyl.