Hydrogen Sulfide → HCID 23327038, compound

HRID 1379987Notes

Reaction equation

HRID 1379987 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([CH:14]=[CH:15][CH:16]=1)[C:5]([NH:7][CH:8]([O:11][CH2:12][CH3:13])[C:9]#[N:10])=[O:6].C(N(CC)CC)C.[SH2:24]>C1(C)C=CC=CC=1>[Cl:1][C:2]1[CH:3]=[C:4]([CH:14]=[CH:15][CH:16]=1)[C:5]([NH:7][CH:8]([O:11][CH2:12][CH3:13])[C:9]([NH2:10])=[S:24])=[O:6]

Participants

5

Reactant 3

HCID 402Hydrogen SulfideHCID 8471TriethylamineHCID 57144111HCID 57144111, compound

Product 1

HCID 23327038HCID 23327038, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Into a solution of 3-chlorobenzoylamino(ethoxy) acetonitrile (1 g) in toluene (50 ml) containing triethylamine (1 g) was passed hydrogen sulphide gas. The precipitated product (0.72 g) was collected and crystallised from chloroform-light petroleum. m.p. 136°-137°.

Workup

  1. customThe precipitated product (0.72 g) was collected
  2. customcrystallised from chloroform-light petroleum

Sources & evidence

ORD record
ord-5909d627c92549f2b63eb144dde32d97
Source dataset
uspto-grants-1986_04
Patent number
US04579581

Reaction notes

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