HRID1380708

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8471

Triethylamine

C6H15N

结构：CC(C)(C)c1cc(Sc2cc(C(C)(C)C)cc(C(C)(C)C)c2O)c(O)c(C(C)(C)C)c1

HCID10898437

未命名化合物

HCID57353436

(Dichloromethyl)silane

CH4Cl2Si

PRODUCTS

生成物

结构：C[SiH]1Oc2c(cc(C(C)(C)C)cc2C(C)(C)C)Sc2cc(C(C)(C)C)cc(C(C)(C)C)c2O1

HCID123391060

未命名化合物

收率 48.7%

PROCEDURE

实验过程

Utilizing the procedure of Example 1, this compound is prepared from 5.7 grams (0.05 mole) dichloromethylsilane, 22.1 grams (0.05 mole) 2,2'-thiobis(4,6-di-t-butylphenol), and 10.1 grams (0.10 mole) triethylamine. Recrystallization twice from acetone-toluene gives 11.8 grams (48% yield) of white crystals, mp 178°-180° C.

WORKUP

后处理

customRecrystallization twice from acetone-toluene