Hydrochloric Acid → HCID 13393461, compound

HRID 1381049Notes

Reaction equation

HRID 1381049 reaction equation
[OH:1][C:2]1[CH:10]=[CH:9][C:8]([C:11](=[O:29])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])=[CH:7][C:3]=1[C:4]([OH:6])=[O:5].[BH4-].[Na+].Cl>C(O)C>[OH:1][C:2]1[CH:10]=[CH:9][C:8]([CH:11]([OH:29])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])=[CH:7][C:3]=1[C:4]([OH:6])=[O:5]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 4311764Sodium borohydrideHCID 51009112-Hydroxy-5-(1-oxooctadecyl)benzoic acid

Product 1

HCID 13393461HCID 13393461, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

2-Hydroxy-5-(1-oxooctadecyl)benzoic acid (1.0 g) was added to 5 ml absolute ethanol, followed by 94 mg of NaBH4. The mixture was stirred at room temperature for 2 hours, then added to 10 ml of 0.1N HCl to give a solid. The solid was filtered, washed with 10 ml of water, dried in air and then at a pressure of 0.5 mm Hg at room temperature for about 65 hours to give the title compound, m.p. ca. 102° C. ##STR10##

Workup

  1. customto give a solid
  2. filtrationThe solid was filtered
  3. washwashed with 10 ml of water
  4. customdried in air

Sources & evidence

ORD record
ord-91add2c63d6e4725af915ce3cb43599f
Source dataset
uspto-grants-1986_04
Patent number
US04584397

Reaction notes

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