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HRID1381064

反应详情

EQUATION

反应方程式

HRID 1381064 的结构方程式

REACTANTS

反应物

3
结构：C[C@]12CCC(=O)C=C1CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
HCID6128

4-Androstene-3,17-dione

C19H26O2

结构：C[C@]12C=CC(=O)C=C1CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
HCID13472

Androsta-1,4-diene-3,17-dione

C19H24O2

结构：C[C@]12CCC(=O)C=C1CC[C@@H]1C2=CC[C@]2(C)C(=O)CC[C@@H]12
HCID239595

9-Dehydroandrostenedione

C19H24O2

PRODUCTS

生成物

1
结构：C[C@]12CCC(=O)C=C1CC[C@H]1[C@@H]3CCC(=O)[C@@]3(C)CC[C@@]12O
HCID10425017

9α-hydroxyandrost-4-en-3,17-dione

C19H26O3

PROCEDURE

实验过程

We have carried on investigations with attention to the fact that corticoids can be prepared through fewer steps from the aforementioned androst-4-ene-3,17-dione, androsta-1,4-diene-3,17-dione or androsta-4,9(11) -diene-3,17-dione which has recently be produced inexpensively and in a large scale from 9α-hydroxy-androst-4ene-3,17-dione which has also recently be produced by a fermentative process.