N-(2-Nitrophenyl)-2-pyridinemethanamine → HCID 23323574, compound

HRID 1381104Notes

Reaction equation

HRID 1381104 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[CH2:7][NH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[N+:15]([O-])=O>[Ni].CO>[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[CH2:7][NH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[NH2:15]

Participants

4

Reactant 1

HCID 13423753N-(2-Nitrophenyl)-2-pyridinemethanamine

Product 1

HCID 23323574HCID 23323574, compound

Reagents, catalysts & solvents 2

HCID 935NickelCatalystHCID 887MethanolSolvent

Procedure

10 g of N-2-picolyl-o-nitroaniline are hydrogenated with Raney nickel in methanol at room temperature to give the o-phenylenediamine derivative which remains as an oil, after the catalyst has been filtered off and the solvent has been evaporated in vacuo.

Sources & evidence

ORD record
ord-e8df4429a74b4b418a7a793fca64d43d
Source dataset
uspto-grants-1986_04
Patent number
US04585775

Reaction notes

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