HCID 21276215, compound → (10-Bromo-1-anthracenyl)methanol

HRID 1381736Notes

Reaction equation

HRID 1381736 reaction equation
[Br:1][C:2]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[C:16](O)=[O:17]>C1COCC1>[Br:1][C:2]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[CH2:16][OH:17]

Participants

3

Reactant 1

HCID 21276215HCID 21276215, compound

Product 1

HCID 13375398(10-Bromo-1-anthracenyl)methanol

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

10-Bromo-1-anthracenecarboxylic acid made from example 2B by the procedure of E. Barnett, J. W. Cook, and H. H. Grainger, Ber. 57 B, 1775 (1924), was reduced with BH3 in THF by the procedure outlined in 2C to give (10-bromo-1-anthryl)methanol mp 125°-127°, (EtOAc/hexane), (C, H, Br).

Sources & evidence

ORD record
ord-718dafb78e014ff585704365454bdb82
Source dataset
uspto-grants-1989_02
Patent number
US04803226

Reaction notes

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