Dimethylformamide → HCID 14370017, compound

HRID 1381747Notes

Reaction equation

HRID 1381747 reaction equation
[CH2:1]([O:5][C:6]1[C:19]2[C:14](=[CH:15][CH:16]=[CH:17][CH:18]=2)[CH:13]=[C:12]2[C:7]=1[CH:8]=[CH:9][CH:10]=[CH:11]2)[CH2:2][CH2:3][CH3:4].CN([CH:23]=[O:24])C>>[CH2:1]([O:5][C:6]1[C:19]2[C:14](=[CH:15][CH:16]=[CH:17][CH:18]=2)[C:13]([CH:23]=[O:24])=[C:12]2[C:7]=1[CH:8]=[CH:9][CH:10]=[CH:11]2)[CH2:2][CH2:3][CH3:4]

Participants

3

Reactant 2

HCID 6228DimethylformamideHCID 13287349HCID 13287349, compound

Product 1

HCID 14370017HCID 14370017, compound

Procedure

10-Butoxyanthracene was formylated using DMF as both solvent and electrophile by the procedure of E. Campaigne and W. L. Archer, J. Amer. Chem. Soc. 75 989 (1953), affording 10-butoxy-9-anthracenecarbaldehyde mp 65°-67°, (pentane), (C, H).

Sources & evidence

ORD record
ord-d7a87e241a074f35a85da8ec83dd28a5
Source dataset
uspto-grants-1989_02
Patent number
US04803226

Reaction notes

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