HRID1381910

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID2766374

Methyl 4-(1H-imidazol-1-yl)benzoate

C11H10N2O2

HCID6394114

N',N'-dibenzylethane-1,2-diamine

C16H20N2

PRODUCTS

生成物

结构：O.O=C(NCCN(Cc1ccccc1)Cc1ccccc1)c1ccc(-n2ccnc2)cc1.O=C(NCCN(Cc1ccccc1)Cc1ccccc1)c1ccc(-n2ccnc2)cc1

HCID67833593

未命名化合物

PROCEDURE

实验过程

Heat 4.23 g (21.0 mmol) of 4-(1H-imidazol-1-yl)benzoic acid methyl ester and 5.00 g (21.0 mmol) of N,N-dibenzylethylenediamine in 10 mL of xylenes at reflux for about 48 hr. Cool the solution to room temperature. Filter to obtain crystals of the title compound.

WORKUP

后处理

temperatureat reflux for about 48 hr
filtrationFilter

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c768e08e13ee4479b9ccd4c63185e2fa
来源数据集: uspto-grants-1989_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04804662
来源说明: uspto-grants-1989_02

反应 SMILES

C[O:2][C:3](=[O:15])[C:4]1[CH:9]=[CH:8][C:7]([N:10]2[CH:14]=[CH:13][N:12]=[CH:11]2)=[CH:6][CH:5]=1.[CH2:16]([N:23]([CH2:27][C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)[CH2:24][CH2:25][NH2:26])[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>>[OH2:2].[C:28]1([CH2:27][N:23]([CH2:16][C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)[CH2:24][CH2:25][NH:26][C:3](=[O:15])[C:4]2[CH:5]=[CH:6][C:7]([N:10]3[CH:14]=[CH:13][N:12]=[CH:11]3)=[CH:8][CH:9]=2)[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=1.[C:17]1([CH2:16][N:23]([CH2:24][CH2:25][NH:26][C:3](=[O:15])[C:4]2[CH:5]=[CH:6][C:7]([N:10]3[CH:14]=[CH:13][N:12]=[CH:11]3)=[CH:8][CH:9]=2)[CH2:27][C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=1