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HRID1381992

反应详情

EQUATION

反应方程式

HRID 1381992 的结构方程式

REACTANTS

反应物

3
结构：O=S(=O)(O)O
HCID1118

Sulfuric acid

H2O4S

结构：O=[N+]([O-])[O-].[K+]
HCID24434

Potassium nitrate

KNO3

结构：Cc1c(Cl)ccc(C(=O)O)c1Cl
HCID13235951

2,4-Dichloro-3-methylbenzoic acid

C8H6Cl2O2

PRODUCTS

生成物

1
结构：Cc1c(Cl)c(C(=O)O)cc([N+](=O)[O-])c1Cl
HCID13657443

2,4-Dichloro-3-methyl-5-nitrobenzoic acid

C8H5Cl2NO4

CONDITIONS

反应条件

温度
50 °C

PROCEDURE

实验过程

30 g of 2,4-dichloro-3-methylbenzoic acid are initially introduced into 83 ml of concentrated H2SO4. 16.7 g of KNO3 are added in portions with ice cooling. The mixture is subsequently warmed at 50° C. for a further 2 hours and then poured onto ice. The nitro compound is isolated and recrystallized from toluene. Melting point 152°-4° C., yield: 24 g.

WORKUP

后处理

  1. additionpoured onto ice