HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,4-Dihydroxy-2,2,6,6-tetramethylpiperidine → 2,4,8,10-Tetra-tert-butyl-6-[1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yloxy]-dibenzo[d,g][1,3,2]dioxaphosphocin
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,4-Dihydroxy-2,2,6,6-tetramethylpiperidine | HCID 5395 | — |
| Reactant | Phosphorus trichloride | HCID 24387 | — |
| Reactant | 2,2'-Methylenebis(4,6-di-tert-butylphenol) | HCID 84391 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | 2,4,8,10-Tetra-tert-butyl-6-[1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yloxy]-dibenzo[d,g][1,3,2]dioxaphosphocin | HCID 70388782 | — |
Reaction Steps
The above-named compound is prepared by the general procedure of Example 1 by reacting 8.8 ml of phosphorous trichloride, 42.54 grams of 2,2'-methylene bis-(4,6-di-tert-butylphenol), 36.8 ml of triethylamine and 11.03 grams of 1,4-dihydroxy-2,2,6,6-tetramethylpiperidine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04808645 |
| Source dataset | uspto-grants-1989_02 |
| ORD ID | ord-c36ed012a8e6492e933ac9657f88d11d |
| Source note | uspto-grants-1989_02 |