HRID1383027

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID5395

1,4-Dihydroxy-2,2,6,6-tetramethylpiperidine

C9H19NO2

HCID24387

Phosphorous trichloride

Cl3P

结构：CC(C)(C)c1cc(Cc2cc(C(C)(C)C)cc(C(C)(C)C)c2O)c(O)c(C(C)(C)C)c1

HCID84391

2,2′-Methylenebis[4,6-bis(1,1-dimethylethyl)phenol]

C29H44O2

PRODUCTS

生成物

结构：CC(C)(C)c1cc2c(c(C(C)(C)C)c1)OP(OC1CC(C)(C)N(O)C(C)(C)C1)Oc1c(cc(C(C)(C)C)cc1C(C)(C)C)C2

HCID70388782

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8471

Triethylamine

C6H15N

PROCEDURE

实验过程

The above-named compound is prepared by the general procedure of Example 1 by reacting 8.8 ml of phosphorous trichloride, 42.54 grams of 2,2'-methylene bis-(4,6-di-tert-butylphenol), 36.8 ml of triethylamine and 11.03 grams of 1,4-dihydroxy-2,2,6,6-tetramethylpiperidine.

WORKUP

后处理

customThe above-named compound is prepared by the general procedure of Example 1

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c36ed012a8e6492e933ac9657f88d11d
来源数据集: uspto-grants-1989_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04808645
来源说明: uspto-grants-1989_02

反应 SMILES

[P:1](Cl)(Cl)Cl.[CH2:5]([C:21]1[CH:26]=[C:25]([C:27]([CH3:30])([CH3:29])[CH3:28])[CH:24]=[C:23]([C:31]([CH3:34])([CH3:33])[CH3:32])[C:22]=1[OH:35])[C:6]1[CH:11]=[C:10]([C:12]([CH3:15])([CH3:14])[CH3:13])[CH:9]=[C:8]([C:16]([CH3:19])([CH3:18])[CH3:17])[C:7]=1[OH:20].[OH:36][N:37]1[C:42]([CH3:44])([CH3:43])[CH2:41][CH:40]([OH:45])[CH2:39][C:38]1([CH3:47])[CH3:46]>C(N(CC)CC)C>[C:27]([C:25]1[CH:24]=[C:23]([C:31]([CH3:34])([CH3:33])[CH3:32])[C:22]2[O:35][P:1]([O:45][CH:40]3[CH2:41][C:42]([CH3:43])([CH3:44])[N:37]([OH:36])[C:38]([CH3:47])([CH3:46])[CH2:39]3)[O:20][C:7]3[C:8]([C:16]([CH3:19])([CH3:18])[CH3:17])=[CH:9][C:10]([C:12]([CH3:15])([CH3:13])[CH3:14])=[CH:11][C:6]=3[CH2:5][C:21]=2[CH:26]=1)([CH3:30])([CH3:29])[CH3:28]