Hydrochloric Acid → HCID 14047793, compound

HRID 1383033Notes

Reaction equation

HRID 1383033 reaction equation
O[CH2:2][N:3]1[CH2:7][CH2:6][N:5]([CH2:8]O)[C:4]1=[O:10].[C:11]([C:15]1[CH:16]=[C:17]([SH:26])[CH:18]=[C:19]([C:22]([CH3:25])([CH3:24])[CH3:23])[C:20]=1[OH:21])([CH3:14])([CH3:13])[CH3:12].Cl>CO>[C:11]([C:15]1[CH:16]=[C:17]([S:26][CH2:2][N:3]2[CH2:7][CH2:6][N:5]([CH2:8][S:26][C:17]3[CH:16]=[C:15]([C:11]([CH3:12])([CH3:13])[CH3:14])[C:20]([OH:21])=[C:19]([C:22]([CH3:25])([CH3:24])[CH3:23])[CH:18]=3)[C:4]2=[O:10])[CH:18]=[C:19]([C:22]([CH3:25])([CH3:24])[CH3:23])[C:20]=1[OH:21])([CH3:14])([CH3:13])[CH3:12]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 87042-Imidazolidinone, 1,3-bis(hydroxymethyl)-HCID 703702,6-Di-tert-butyl-4-mercaptophenol

Product 1

HCID 14047793HCID 14047793, compoundYield 78%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A solution of 3.65 grams of 1,3-bis(hydroxymethyl)-2-imidazolidone and 11.92 grams of 3,5-di-t-butyl-4-hydroxybenzenethiol in 100 ml of methyl alcohol was treated with anhydrous hydrogen chloride. The reaction mixture was cooled and the product recrystallized from methyl alcohol to give 11.43 grams of white solid, m.p. 173°-176° C.

Workup

  1. temperatureThe reaction mixture was cooled
  2. customthe product recrystallized from methyl alcohol

Sources & evidence

ORD record
ord-33a08189a3ec49c283dff557718318a0
Source dataset
uspto-grants-1989_02
Patent number
US04808644

Reaction notes

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