Ethanol → HCID 86739234, compound

HRID 1388263Notes

Reaction equation

HRID 1388263 reaction equation
[CH3:1][C:2]1([CH3:14])[C@H:4](/[CH:5]=[CH:6]/[C:7]([O:9][CH3:10])=[O:8])[C@H:3]1[C:11](Cl)=[O:12].[CH2:15]([OH:17])[CH3:16]>C1C=CC=CC=1.C(Cl)(Cl)Cl>[CH3:1][C:2]1([CH3:14])[C@H:4](/[CH:5]=[CH:6]/[C:7]([O:9][CH3:10])=[O:8])[C@H:3]1[C:11]([O:17][CH2:15][CH3:16])=[O:12]

Participants

5

Reactant 2

HCID 702EthanolHCID 131713383HCID 131713383, compound

Product 1

HCID 86739234HCID 86739234, compound

Reagents, catalysts & solvents 2

HCID 241BenzeneSolventHCID 6212ChloroformSolvent

Procedure

Using the procedure of Example 3, 2.7 g of (1R,trans) 2,2-dimethyl-3-[(E)-3-methoxy-3-oxo-1-propenyl]-cyclopropane-1-carboxylic acid chloride in 12.5 ml of benzene and 1 ml of ethanol were reacted to obtain 1.31 g of ethyl (1R,trans) 2,2-dimethyl-3-[(E)-3-methoxy-3-oxo-1-propenyl]-cyclopropane-1-carboxylate with a specific rotation of [α]D20 =+93°±1.5° (c=1% in chloroform).

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-40e12e7097d945228f0775a18a246ad1
Source dataset
uspto-grants-1984_02
Patent number
US04431576

Reaction notes

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