Benzyl Alcohol → HCID 86739236, compound

HRID 1388265Notes

Reaction equation

HRID 1388265 reaction equation
[CH3:1][C:2]1([CH3:14])[C@H:4](/[CH:5]=[CH:6]/[C:7]([O:9][CH3:10])=[O:8])[C@H:3]1[C:11](Cl)=[O:12].[CH2:15]([OH:22])[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1>C1C=CC=CC=1.C(Cl)(Cl)Cl>[CH3:1][C:2]1([CH3:14])[C@H:4](/[CH:5]=[CH:6]/[C:7]([O:9][CH3:10])=[O:8])[C@H:3]1[C:11]([O:22][CH2:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)=[O:12]

Participants

5

Reactant 2

HCID 244Benzyl AlcoholHCID 131713383HCID 131713383, compound

Product 1

HCID 86739236HCID 86739236, compound

Reagents, catalysts & solvents 2

HCID 241BenzeneSolventHCID 6212ChloroformSolvent

Procedure

Using the procedure of Example 3, 12.5 ml of 1 M/l of (1R,trans) 2,2-dimethyl-3-[(E)-3-methoxy-3-oxo-1-propenyl]-cyclopropane-1-carboxylic acid chloride in benzene and 1.35 ml of benzyl alcohol were reacted to obtain 1.77 g of benzyl (1R,trans) 2,2-dimethyl-3[(E)-3-methoxy-3-oxo-1-propenyl]-cyclopropane-1-carboxylate with a specific rotation of [α]D20 =+47.5°±1.5° (c=1% in chloroform).

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-72ce1b4cced04cef8fc20dbec70f33b2
Source dataset
uspto-grants-1984_02
Patent number
US04431576

Reaction notes

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