tert-Butanol → HCID 86739241, compound

HRID 1388269Notes

Reaction equation

HRID 1388269 reaction equation
[CH3:1][C:2]1([CH3:14])[C@@H:4](/[CH:5]=[CH:6]/[C:7]([O:9][CH3:10])=[O:8])[C@H:3]1[C:11](Cl)=[O:12].[C:15]([OH:19])([CH3:18])([CH3:17])[CH3:16]>C1C=CC=CC=1.C(Cl)(Cl)Cl>[CH3:1][C:2]1([CH3:14])[C@@H:4](/[CH:5]=[CH:6]/[C:7]([O:9][CH3:10])=[O:8])[C@H:3]1[C:11]([O:19][C:15]([CH3:18])([CH3:17])[CH3:16])=[O:12]

Participants

5

Reactant 2

HCID 6386tert-ButanolHCID 131713384HCID 131713384, compound

Product 1

HCID 86739241HCID 86739241, compound

Reagents, catalysts & solvents 2

HCID 241BenzeneSolventHCID 6212ChloroformSolvent

Procedure

Using the procedure of Example 3, 1.51 g of (1R,cis) 2,2-dimethyl-3-[(E)-3-methoxy-3-oxo-1-propenyl]-cyclopropane-1-carboxylic acid chloride in benzene and 0.754 ml of tert.-butanol were reacted to obtain 0.235 g of tert.-butyl (1R,cis) 2,2-dimethyl-3-[(E)-3-methoxy-3-oxo-1-propenyl]-cyclo-propane-1-carboxylate with a specific rotation of [α]D20 =-23°±1.5°(c=0.9% in chloroform).

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-1c619c93c76c4677a117bbaf916237ee
Source dataset
uspto-grants-1984_02
Patent number
US04431576

Reaction notes

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