Triphenylphosphine → HCID 86739283, compound

HRID 1388880Notes

Reaction equation

[I:1][CH2:2][CH2:3]/[CH:4]=[CH:5]\[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[C:14]1([P:20]([C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)[C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>>[I-:1].[CH2:2]([P+:20]([C:21]1[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=1)([C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)[CH2:3]/[CH:4]=[CH:5]\[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

Participants

Reactant 2

HCID 11776Triphenylphosphine

HCID 86739285HCID 86739285, compound

Product 1

HCID 86739283HCID 86739283, compoundYield 100.4%

Conditions

Temperature: 90 °C

Procedure

A mixture of 0.43 g (1.46 mmoles) of (Z)-1-iodo-3-dodecene and 0.38 g (1.45 mmoles) of triphenylphosphine was heated at 90° C. for 3 hrs. under argon to produce 0.81 g of [(Z)-3-dodecen-1-yl]triphenylphosphonium iodide. This material was used without further purification.

Sources & evidence

ORD record: ord-37142ddaf3cd4ce3af7e9890f5ade83b
Source dataset: uspto-grants-1984_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04434101

Reaction notes

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