Hydrogen Bromide → HCID 20482535, compound

HRID 1389672Notes

Reaction equation

HRID 1389672 reaction equation
[BrH:1].[CH2:2]([NH:13][C:14]1[CH:22]=[CH:21][C:17]([C:18]([OH:20])=[O:19])=[CH:16][CH:15]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]=[CH2:12].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>COCCOC>[Br:1][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][NH:13][C:14]1[CH:15]=[CH:16][C:17]([C:18]([OH:20])=[O:19])=[CH:21][CH:22]=1

Participants

5

Reactant 3

HCID 260Hydrogen BromideHCID 7187Benzoyl PeroxideHCID 20482503HCID 20482503, compound

Product 1

HCID 20482535HCID 20482535, compound

Reagents, catalysts & solvents 1

HCID 80711,2-DimethoxyethaneSolvent

Procedure

Anhydrous hydrogen bromide is passed rapidly into a solution of 5 g. of 4-(10-undecenylamino)benzoic acid and 1 g. of dibenzoyl peroxide in 300 ml. of 1,2-dimethoxyethane for 1 hour. Partial evaporation of the solvent affords a crystalline solid which is separated by filtration and recrystallized from etherpetroleum ether to yield the product as a white solid.

Workup

  1. customPartial evaporation of the solvent
  2. customaffords a crystalline solid which
  3. customis separated by filtration
  4. customrecrystallized from etherpetroleum ether

Sources & evidence

ORD record
ord-c8f3c47fac18424db7af0cad802a8552
Source dataset
uspto-grants-1981_01
Patent number
US04245097

Reaction notes

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