Diethanolamine → HCID 86737455, compound

HRID 1389947Notes

Reaction equation

HRID 1389947 reaction equation
[Cl:1][C:2]1[C:7]([Cl:8])=[CH:6][CH:5]=[C:4]([Cl:9])[C:3]=1[CH:10](C1C=CC=CC=1C)[C:11]([OH:13])=[O:12].[NH:21]([CH2:25][CH2:26][OH:27])[CH2:22][CH2:23][OH:24]>O(CC)CC>[NH:21]([CH2:25][CH2:26][OH:27])[CH2:22][CH2:23][OH:24].[Cl:1][C:2]1[C:7]([Cl:8])=[CH:6][CH:5]=[C:4]([Cl:9])[C:3]=1[CH:10]([NH:21][C:25]1[CH:26]=[CH:4][CH:3]=[CH:2][C:7]=1[CH3:6])[C:11]([OH:13])=[O:12]

Participants

4

Reactant 2

HCID 8113DiethanolamineHCID 20296024HCID 20296024, compound

Product 1

HCID 86737455HCID 86737455, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

To a stirred solution of 8.62 parts of 2,3,6-trichloro-α-(2-methylphenyl)benzeneacetic acid in 175 parts of 1,1'-oxy-bisethane are added 2.62 parts of 2,2'-iminobis[ethanol] and the whole is stirred for 1 hour at room temperature. The precipitated product is filtered off and stirred in 70 parts of 1,1'-oxybisethane. It is filtered off again and dried, yielding 10 parts of 2,3,6-trichloro-α-[(2-methylphenyl)amino]benzeneacetic acid compound with 2,2'-iminobis[ethanol] (1:1); mp. 145.2° C.

Workup

  1. filtrationThe precipitated product is filtered off
  2. stirringstirred in 70 parts of 1,1'-oxybisethane
  3. filtrationIt is filtered off again
  4. customdried

Sources & evidence

ORD record
ord-1894637abb1d40e59d67f16cf38c50ac
Source dataset
uspto-grants-1981_01
Patent number
US04246429

Reaction notes

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