Water → HCID 19842598, compound

HRID 1390176Notes

Reaction equation

HRID 1390176 reaction equation
[Na].[I-].[C:3]([CH2:5][CH2:6][P+:7](CCC#N)([CH2:12][CH2:13][C:14]#[N:15])[CH2:8][CH2:9][O:10][CH3:11])#[N:4].O.C(Cl)(Cl)Cl>CO>[C:3]([CH2:5][CH2:6][P:7]([CH2:12][CH2:13][C:14]#[N:15])[CH2:8][CH2:9][O:10][CH3:11])#[N:4]

Participants

6

Reactant 4

HCID 962WaterHCID 6212ChloroformHCID 5360545SodiumHCID 20520070HCID 20520070, compound

Product 1

HCID 19842598HCID 19842598, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

1.55 g of sodium are dissolved in 100 ml of absolute methanol under an atmosphere of argon and then 26 g (0.0685 mole) of tris-(β-cyanoethyl)-2-methoxyethyl-phosphonium iodide are added to this solution. The solution is refluxed for 4 hours. After the mixture has been poured into water, extraction is performed with three 40 ml portions of chloroform. The chloroform solution is dried over magnesium sulphate, the solvent is evaporated and the oily residue distilled in a high vacuum.

Workup

  1. temperatureThe solution is refluxed for 4 hours
  2. dry with materialThe chloroform solution is dried over magnesium sulphate
  3. customthe solvent is evaporated
  4. distillationthe oily residue distilled in a high vacuum

Sources & evidence

ORD record
ord-3b12450557754a49a931e5938d1173c2
Source dataset
uspto-grants-1979_02
Patent number
US04138256

Reaction notes

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