HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium hydride → Sodium 4-chloromethyl-2, 6-di-tert-butylphenoxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | 2,6-Di-tert-butyl-4-(chloromethyl)phenol | HCID 12378601 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Sodium 4-chloromethyl-2, 6-di-tert-butylphenoxide | HCID 23699397 | — |
Reaction Steps
To a stirred suspension of sodium hydride (2 g.) in dry dimethyl formamide (20 ml.) was added dropwise a solution of 4-chloromethyl-2, 6-di-tert-butylphenol (10 g.) in dimethyl formamide (40 ml.) at 25°-30° C. The mixture was stirred for 30 minutes, during which gas evolution ceased, so as to produce a solution of sodium 4-chloromethyl-2, 6-di-tert-butylphenoxide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04138389 |
| Source dataset | uspto-grants-1979_02 |
| ORD ID | ord-ed335a9a33ba478a905286c3c5f80dc1 |
| Source note | uspto-grants-1979_02 |