HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Bicarbonate → HCID 22748569, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Bicarbonate | HCID 516892 | — |
| Reactant | Water ethanol | HCID 19096565 | — |
| Reactant | HCID 22748559 | HCID 22748559 | — |
| Catalyst | Calcium Palladium Carbonate | HCID 12000666 | — |
| Product | HCID 22748569 | HCID 22748569 | 41% |
Reaction Steps
Ethyl 6,6-dichloro-3-ethyl-7-oxo-1-aza-4-oxabicyclo[3.2.0]heptane-2-carboxylate (e21) (25mg, 0.089 m.mole) in EtOH/H2O containing 2 equivalents of NaHCO3 was hydrogenated over Pd/CaCO3 for 45 minutes, extracted into ethyl acetate, dried and evaporated under reduced pressure. Chromatography yielded the title compound (e22) (9 mg, 41%) M+ 247.0612 C10H14ClNO4 requires 247.0611
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04138403 |
| Source dataset | uspto-grants-1979_02 |
| ORD ID | ord-5d29386ab4204ba3b944fab9a29b97ae |
| Source note | uspto-grants-1979_02 |