Methanethiol → 2-Pyrazinyl-ethyl methyl sulfide

HRID 1390242Notes

Reaction equation

HRID 1390242 reaction equation
[CH:1]([C:3]1[CH:8]=[N:7][CH:6]=[CH:5][N:4]=1)=[CH2:2].[CH3:9][SH:10].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>>[CH3:9][S:10][CH2:2][CH2:1][C:3]1[CH:8]=[N:7][CH:6]=[CH:5][N:4]=1

Participants

4

Reactant 3

HCID 878MethanethiolHCID 7187Benzoyl PeroxideHCID 77840Vinylpyrazine

Product 1

HCID 226304002-Pyrazinyl-ethyl methyl sulfide

Procedure

h. 2-Pyrazinyl-ethyl methyl sulfide was prepared by reacting vinylpyrazine [c.f. J.Org.Chem. 27, 1363 (1962)] with methylmercaptan by the action of ultra-violet light and in the presence of benzoyl peroxide by the method described in Acta Chem. Scand. 8, 295 (1954). The product was identified by mass spectrometry. It has a b.p. of 57°-69° C. at 0.05 mm. Hg.

Sources & evidence

ORD record
ord-587579e4b01b4cafa8cc285ec83c174d
Source dataset
uspto-grants-1979_02
Patent number
US04138410

Reaction notes

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