Triethanolamine → HCID 20375633, compound

HRID 1390301Notes

Reaction equation

HRID 1390301 reaction equation
[N:1]([CH2:8][CH2:9][OH:10])([CH2:5][CH2:6][OH:7])[CH2:2][CH2:3][OH:4].[CH2:11]([N:18]1[C:27]2[C:22](=[CH:23][CH:24]=[CH:25][CH:26]=2)[C:21]([CH:28]([CH3:32])[C:29]([OH:31])=[O:30])=[CH:20][C:19]1=[O:33])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>O>[CH2:11]([N:18]1[C:27]2[C:22](=[CH:23][CH:24]=[CH:25][CH:26]=2)[C:21]([CH:28]([CH3:32])[C:29]([OH:31])=[O:30])=[CH:20][C:19]1=[O:33])[C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=1.[N:1]([CH2:8][CH2:9][OH:10])([CH2:5][CH2:6][OH:7])[CH2:2][CH2:3][OH:4]

Participants

4

Reactant 2

HCID 7618TriethanolamineHCID 12802755HCID 12802755, compound

Product 1

HCID 20375633HCID 20375633, compoundYield 94.2%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Triethanolamine (0.243 g.) was added to a stirred suspension of finely powdered α-(1-benzyl-1,2-dihydro-2-oxoquinol-4-yl)propionic acid (0.50 g.) in distilled water (5.0 ml.), and the mixture was stirred overnight at ambient temperature. The solid which had formed was separated and dried in vacuo over phosphorus pentoxide to give triethanolamine α-(1-benzyl-1,2-dihydro-2-oxoquinol-4-yl)propionate (0.7 g.), m.p. 163°-165° C. (decomposition).

Workup

  1. customThe solid which had formed
  2. customwas separated
  3. dry with materialdried in vacuo over phosphorus pentoxide

Sources & evidence

ORD record
ord-03614762b611480ebe7373660a0940e8
Source dataset
uspto-grants-1979_02
Patent number
US04138490

Reaction notes

Loading…