HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium borohydride → 1,5-Di-(3,3-dimethylnorborn-2-yl)-3-pentanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium borohydride | HCID 4311764 | — |
| Reactant | 1,5-Di-(3,3-dimethylnorborn-2-yl)-3-pentanone | HCID 21332846 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 1,5-Di-(3,3-dimethylnorborn-2-yl)-3-pentanol | HCID 21332842 | — |
Reaction Steps
The ketone, 1,5-di-(3,3-dimethylnorborn-2-yl)-3-pentanone (2 grams) was dissolved in 100 ml. of ethanol and stirred with 2 grams of sodium borohydride overnight. The solvent was removed in vacuo and the residue partitioned between ethyl ether and water. The organic layer was dried over sodium sulfate. After filtration, and removal of solvent a colorless oil was obtained that crystallized on standing, m.p. 55° C.-56° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04139559 |
| Source dataset | uspto-grants-1979_02 |
| ORD ID | ord-8e660559ec5a4d1a89cdbf6e555f403d |
| Source note | uspto-grants-1979_02 |