Hydrazine hydrate (1:1) → HCID 21333471, compound

HRID 1390640Notes

Reaction equation

HRID 1390640 reaction equation
[CH3:1][N:2]([CH3:24])[CH2:3][CH2:4][CH2:5][N:6]1[C:14]2[C:9](=[CH:10][C:11]([N+:15]([O-])=O)=[CH:12][CH:13]=2)[CH:8]=[C:7]1[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.O.NN>[Ni].C(O)C>[CH3:24][N:2]([CH3:1])[CH2:3][CH2:4][CH2:5][N:6]1[C:14]2[C:9](=[CH:10][C:11]([NH2:15])=[CH:12][CH:13]=2)[CH:8]=[C:7]1[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1

Participants

5

Reactant 2

HCID 24654Hydrazine hydrate (1:1)HCID 21333498HCID 21333498, compound

Product 1

HCID 21333471HCID 21333471, compound

Reagents, catalysts & solvents 2

HCID 935NickelCatalystHCID 702EthanolSolvent

Procedure

While stirring, 32.3 g (0.1 mol) of 1-(3'-dimethylamino-propyl)-2-phenyl-5-nitro-indole, prepared as in Example 1, was mixed with 15 g (0.3 mol) of hydrazine hydrate, 300 ml of pure absolute ethanol and a small quantity of Raney Nickel.

Sources & evidence

ORD record
ord-6cdcc1f59a6548dcae8d5f331a6eaa74
Source dataset
uspto-grants-1979_02
Patent number
US04139634

Reaction notes

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