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HRID1390745

反应详情

EQUATION

反应方程式

HRID 1390745 的结构方程式

REACTANTS

反应物

3
结构：C[C@@H]1C(=O)C[C@H](C)[C@@]2(CO)C1=CC[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12
HCID70605333

未命名化合物

结构：C[C@@H]1C(=O)CC[C@@]2(CO)C1=CC[C@@H]1[C@@H]2CC[C@]2(C)[C@@H](O)CC[C@@H]12
HCID70605756

未命名化合物

结构：C[C@@H]1C(=O)CC[C@@]2(CO)C1=C[C@@H](C)[C@@H]1[C@@H]2CC[C@]2(C)[C@@H](O)CC[C@@H]12
HCID70605854

未命名化合物

PRODUCTS

生成物

3
结构：C[C@H]1C2=CC[C@@H]3[C@H](CC[C@]4(C)[C@@H](O)CC[C@@H]34)[C@@]2(CO)CC[C@@H]1O
HCID70605537

未命名化合物

结构：C[C@@H]1C=C2[C@H](C)[C@@H](O)CC[C@]2(CO)[C@H]2CC[C@]3(C)[C@@H](O)CC[C@H]3[C@H]12
HCID70605757

未命名化合物

结构：C[C@H]1C2=CC[C@H]3[C@@H]4CC[C@H](O)[C@@]4(C)CC[C@@H]3[C@@]2(CO)[C@@H](C)C[C@@H]1O
HCID70606105

未命名化合物

PROCEDURE

实验过程

Substituting 17β,19-dihydroxy-4α-methyl-5-androsten-3-one, 19-hydroxy-1α,4α-dimethyl-5-androstene-3,17-dione, 17β,19-dihydroxy-4α,7α-dimethyl-5-androsten-3-one, 4α-methyl-17β,19-di(2'-tetrahydropyranyloxy)-5-androsten-3-one and 1α,4α-dimethyl-19-(2'-tetrahydropyranyloxy)-5-androstene-3,17-dione for the 17β,19-dihydroxy-4α,6,17α-trimethyl-5-androsten-3-one above results in the formation of 4α-methyl-5-androstene-3β,17β,19-triol, 1α,4α-dimethyl-5-androstene-3β,17β,19-triol, 4α,7α-dimethyl-5-androstene-3β,17β,19-triol, 4α-methyl-17β,19-di(2'-tetrahydropyranyloxy)-5-androsten-3β-ol and 1α,4α-dimethyl-19-(2'-tetrahydroyranyloxy)-5-androstene-3β,17β-diol, respectively.