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HRID1390781

反应详情

EQUATION

反应方程式

HRID 1390781 的结构方程式

REACTANTS

反应物

3
结构：O
HCID962

Water

H2O

结构：[Al+3].[H-].[H-].[H-].[H-].[Li+]
HCID21226445

未命名化合物

结构：CC(=O)OC[C@]12CC[C@H](O[Si](c3ccccc3)(c3ccccc3)c3ccccc3)CC1=CC[C@@H]1[C@@H]2CC[C@]2(C)[C@@H](O[Si](c3ccccc3)(c3ccccc3)c3ccccc3)CC[C@@H]12
HCID22806919

未命名化合物

PRODUCTS

生成物

1
结构：C[C@]12CC[C@H]3[C@@H](CC=C4C[C@@H](O[Si](c5ccccc5)(c5ccccc5)c5ccccc5)CC[C@@]43CO)[C@@H]1CC[C@@H]2O[Si](c1ccccc1)(c1ccccc1)c1ccccc1
HCID22806917

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCOCC
溶剂HCID3283

Diethyl Ether

C4H10O

2 次

PROCEDURE

实验过程

To an ether solution of 3β,17β-di(triphenylsiloxy)androst-5-en-19-ol acetate is added a suspension of lithium aluminum hydride in ether. After refluxing for a period of one hour, water is cautiously added, the ether solution is separated, dried over sodium sulfate and evaporated under reduced pressure. The residue when purified from an acetone-hexane mixture results in the preparation of the desired 3β,17β-di(triphenylsiloxy)-androst-5-en-19-ol.

WORKUP

后处理

  1. temperatureAfter refluxing for a period of one hour
  2. customthe ether solution is separated
  3. dry with materialdried over sodium sulfate
  4. customevaporated under reduced pressure
  5. customThe residue when purified from an acetone-hexane mixture