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HRID1390785

反应详情

EQUATION

反应方程式

HRID 1390785 的结构方程式

REACTANTS

反应物

2
结构：C[C@]12CC[C@H]3[C@@H](CC=C4C[C@@H](O[Si](c5ccccc5)(c5ccccc5)c5ccccc5)CC[C@@]43CO)[C@@H]1CC[C@@H]2O[Si](c1ccccc1)(c1ccccc1)c1ccccc1
HCID22806917

未命名化合物

结构：C[C@H]1CC(=O)CC2=CC[C@@H]3[C@H](CC[C@]4(C)C(=O)CC[C@@H]34)[C@]21CO
HCID70605334

未命名化合物

PRODUCTS

生成物

2
结构：C[C@]12CC[C@H]3[C@@H](CC=C4C[C@@H](O[Si](c5ccccc5)(c5ccccc5)c5ccccc5)CC[C@@]43C=O)[C@@H]1CC[C@@H]2O[Si](c1ccccc1)(c1ccccc1)c1ccccc1
HCID22806918

未命名化合物

结构：C[C@H]1CC(=O)CC2=CC[C@@H]3[C@H](CC[C@]4(C)C(=O)CC[C@@H]34)[C@]21C=O
HCID86736326

未命名化合物

PROCEDURE

实验过程

Substituting 17β,19-dihydroxy-1α,17α-dimethyl-5-androsten-3-one, 19-hydroxy-1α-methyl-5-androstene-3,17-dione, 17β,19-dihydroxy-4α,6,17α-trimethyl-5-androsten-3-one, 17β-(2'-tetrahydropyranyloxy)-5-androsten-19-ol and 3β,17β-di(triphenylsiloxy)-5-androsten-19-ol for the 17α-methyl-5-androstene-3β,17β,19-triol 3,17-diacetate above results in the preparation of 17β-hydroxy-1α,17α-dimethyl-5-androstene-3,19-dione, 1α-methyl-5-androstene-3,17,19-trione, 17β-hydroxy-4α,6,17α-trimethyl-5-androstene-3,19-dione, 17β-(2'-tetrahydropyranyloxy)-5-androsten-19-one and 3β,17β-di(triphenylsiloxy)-5-androsten-19-one, respectively.