Epichlorohydrin → HCID 20555085, compound

HRID 1391049Notes

Reaction equation

HRID 1391049 reaction equation
[CH2:1]([O:4][C:5]1[C:10]([N+:11]([O-:13])=[O:12])=[CH:9][CH:8]=[CH:7][C:6]=1[OH:14])[CH:2]=[CH2:3].C(=O)([O-])[O-].[K+].[K+].[CH2:21]([CH:23]1[O:25][CH2:24]1)Cl>CC(C)=O>[CH2:1]([O:4][C:5]1[C:10]([N+:11]([O-:13])=[O:12])=[CH:9][CH:8]=[CH:7][C:6]=1[O:14][CH2:21][CH:23]1[O:25][CH2:24]1)[CH:2]=[CH2:3]

Participants

5

Reactant 3

HCID 7835EpichlorohydrinHCID 11430Potassium CarbonateHCID 20555092HCID 20555092, compound

Product 1

HCID 20555085HCID 20555085, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

10.0 g of 2-allyloxy-3-nitrophenol, 27 g of potassium carbonate and 54 ml of epichlorohydrin in 300 ml of acetone are stirred under reflux for 15-20 hours. After filtering the reaction mixture and evaporating the filtrate, crude 2-allyloxy-1-(2,3-epoxy-propoxy)-3-nitrobenzene is obtained and this can be used further as such.

Workup

  1. temperatureunder reflux for 15-20 hours
  2. filtrationAfter filtering the reaction mixture
  3. customevaporating the filtrate

Sources & evidence

ORD record
ord-f43c9b3955db4009b187179dbb54e3bc
Source dataset
uspto-grants-1979_02
Patent number
US04140789

Reaction notes

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